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    • AXIS A Multi-catalysis, cascades and compartimentalization
    • AXIS B Catalysis and Materials for Energy and Environment
    • AXIS C Smart materials and interfaces
    • AXIS D Multifunctional probes and multiscale strategies
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AXIS B Catalysis and Materials for Energy and Environment

AXIS B Catalysis and Materials for Energy and Environment

This theme aims at developing new ways for 1) the production of value-added chemicals from raw materials through catalytic processes, 2) the conversion and storage of energy through physical-chemical processes and 3) the detection, capture and degradation of pollutants.

Innovative Catalytic Methodologies for Biomass conversion and CO2 activation.

Reactions and processes implementing renewable reactants (CO2 and biomass), displaying improved atom-economy and/or functioning under mild conditions are targeted to ultimately provide the bulk and fine chemicals supplied by the chemical industry.

Along these lines,transformations and shortcut catalyzed synthetic routes to value-added chemicals under environmentally friendly conditions, i.e.using clean oxidants or reductants, enzymatic or electrochemical methods, and developing complementary methodologies such as electro- and photocatalysis, microwave, flow chemistry, high-throughput screening, supported homogeneous catalysis, non-conventional media, are looked for.

Energy Conversion and Storage.

The three challenges to tackle are:

1- Development of materials and devices forH2 production, storage and use, based on cost-effective molecular systems or materials as well as catalysts for Proton Exchange Membranes (PEM) or Solid Oxide (SO).

2- Development of molecular systems, materials or devices for the direct conversion of solar energy into chemical energy by photoelectrochemical processes.

3- Development of highly efficient electrochemical storage energy materials for renewable energy production and mobility applications implementing various solutions. High energy and long lifetime electrodes for advanced Li-ion batteries (the most mature), high-energy and stable anodes for Mg-ion batteries (more prospective), and advanced nanostructured materials for supercapacitors (a requirement in the transportation sector) are targeted.

Depollution and remediation.

Depollution processes (including pollutant storage, detection and degradation) based on materials structured at different levels are targeted. Innovative catalytic porous materials exhibiting stability, renewability and eco-compatibility must be developed by integrating chemo-, photo- or electro-responsive molecules, supramolecular assemblies or nanoparticles within adapted matrices (surfaces, polymers or functional materials).

Coordinateurs:

    • Frédéric BANSE
    • Pierre MIALANE
    • Thierry GACOIN

Lire la suite...
AXIS A Multi-catalysis, cascades and compartimentalization

AXIS A Multi-catalysis, cascades and compartimentalization

Synthetic organic chemistry has considerably expanded in the last thirty years with the development of methods that theoretically enable the synthesis of any kind of complex natural products, even on a large scale. However, many issues remain to be addressed because new regulations and environmental constraints enforce to envision a more efficient organic synthesis that must combine the issues of conversion, selectivity, diversity and complexity with that of sustainability. The organic chemists should now include in their synthetic planning the notions of atom- and step-economy, toxicity of waste, energy cost, and recycling process. The design of multicatalytic cascades for the formation of complex molecules, to this end, can provide a solution to this challenge.

AxeA 1

The search for modular catalytic systems able to mediate the formation of complex products, whose structure can be fine-tuned
according to the reaction conditions, should provide a unique tool to create libraries of high added value molecules from simple synthons ideally derived from biomass.
Accordingly, the main goal of this priority theme is the design of a chemical toolbox that allows for performing multi-catalyzed cascade transformations leading to the one pot formation of complex molecular architectures.
This challenging issue is addressed following different approaches:
- The design, synthesis and characterization of multifunctional catalysts,

AxeA 2

- The design of multicatalytic systems through compartmentalization,

AxeA 3

- The development of new cascade reactions towards molecular diversity and complexity.

AxeA 4

Coordinateurs:

    • Philippe DAUBAN
    • Emmanuelle SCHULZ
    • Xavier MOREAU

Lire la suite...
AXIS C Smart materials and interfaces

AXIS C Smart materials and interfaces

Smart or active materials have properties significantly impacted in a controlled fashion by external stimuli and are used in various fields such as sensors, information processing, memories, lighting systems. The current developments deal with 1) materials that can perform more than one task or that can be manipulated by several independent stimuli; 2) novel systems with reduced environmental impact or increased durability; 3) devices with elaborate architectures to tune the coupling between the materials and their environment. Three objectives has defined:

Fine tuning of light parameters in emissive materials.Emission of lightby materials can betriggered by different stimuli (light, electricity…), which is of special interest in lighting and sensing to control intensity, color, polarization and direction of the emitted light. Conjugated molecular materials, specific phosphorescent metal-ion, and doping of inorganic materials will be considered. Devices design and its effect on performance and stability in operating conditions will be taken care of. The challenge will be to isolate new materials with controlled compositions or shapes that allow for fine tuning of their properties.

Design of molecules, inorganic compounds, hybrid materials or heterostructures as smart responsive materialsfor the elaboration of sensors, systems dedicated to environmental and security issues, optoelectronic and information technologies. The search for new molecular architectures, exotic states of matter, synergetic effects through magnetic exchange, energy transfer or mechanical coupling within heterostructures, compounds at the verge of phase transitions are efficient approaches to reversibly change material properties by an external trigger. The main challenge is a deep understanding of the underlying mechanisms to better control response time, increase sensitivity by optimizing the coupling between the environment and the transducing element and improving specificity for sensing and monitoring applications.

Bioinspired and biointegrated materials.Multi-component nanoparticles with complementary functions(drug loading, active targeting, imaging…) or stimuli-responsive properties will be developed for drug delivery and bioimaging.Thin films and nanostructured biosurfacesof various composition, surface functionalization and microstructural organization (Langmuir-Blodgett films, heterostructures…), will also be designed to build responsive devices (biosensors, biofuel cells, biochip…) or anti-biofouling surfaces. The challenge lies in the control of the spatial organization, stability and confinement of active bio-components on solid surfaces, improvement of charge transfer kinetics.

Axe C 1

Coordinateurs:

  • Clémence ALLAIN
  • Damien AUREAU
  • Denis TONDELIER

Lire la suite...
AXIS D Multifunctional probes and multiscale strategies

AXIS D Multifunctional probes and multiscale strategies

This theme builds on the achievements of the previous T1 axis, but also targets interaction with a widened community of physical chemists and life-science chemists from Paris-Saclay. It will base on state-of-the-art experimental platforms and computational facilities, and develop new analytical and computational methods.
Synergy between highly diverse platforms, methodology skills, and chemists, will be fostered to bring new ad hoc models and multiscale and multi-method analytical approaches, to address questions on complex systems and functions, in which chemistry brings essential insights. It encompasses the development of multi-dimensional analytical innovative couplings, the prediction of molecular structures, the characterization of reaction and interactions pathways, the use and development of both experimental methods and multi-scale computational modeling for a better micro- and macroscopic understanding of catalysis, chemical reactivity in the condensed and gas phases, at the interfaces, or in confined materials. The results will contribute to the other priority themes by helping deciphering and/or predicting the fundamental processes underlying the properties and functions of molecules and materials prepared or designed within these themes.
Chemistry has strong interfaces with physics, physical chemistry and life science. The underlying fundamental processes driving the properties of (bio)molecular architectures or materials are profoundly multiscale and multifunctional, and crucial for the design of these objects within the CHARM3AT priority themes. The theoretical and experimental platforms (including national facilities such as Synchrotron SOLEIL, IR-RMN, FRISBI, etc.) available within the perimeter of Paris-Saclay will be used to reinforce the partnership between chemists, physicists and biologists.

AxisD 1

Topologic and electronic density driven generation of alkali cation complexes”
H. Boufroura, S. Poyer, A. Gaucher, C. Huin, J-Y. Salpin, G. Clavier, D. Prim
Chem. Eur. J., 24, 8656-8663 (2018)

AxisD 2

Figure. Gauche : Spectre RMN 31P d’un cluster de cuivre (haut), et spectre simplifié (milieu), permettant une mesure aisée des couplages J pour les 3 sites P1, P2 et P3. Droite : comparaison entre déplacements chimiques du 31P expérimentaux et calculés, montrant le bon accord fournit par le code CASTEP.

AxisD 3

Figure. LC-MS (left) and ion mobility experiments (right) onto [M+Ag]+ ions using different solvent conditions.

Coordinateurs:

    • Jean-Yves SALPIN
    • Carine VAN HEIJNOORT
    • Fabienne BERTHIER

Lire la suite...
  •   AXIS B Catalysis and Materials for Energy and Environment AXIS B Catalysis and Materials for Energy and Environment Tagline
  •   AXIS A Multi-catalysis, cascades and compartimentalization AXIS A Multi-catalysis, cascades and compartimentalization Tagline
  •   AXIS C Smart materials and interfaces AXIS C Smart materials and interfaces Tagline
  •   AXIS D Multifunctional probes and multiscale strategies AXIS D Multifunctional probes and multiscale strategies Tagline
  •  
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Voir toutes les actualités

Actualités

Nouveau spectromètre de masse au LAMBE

Le laboratoire Analyse et Modélisation pour le Biologie et l'Environnement vient de faire l'acquisition d'un nouveau spectromètre de masse. Obtenu grâce au soutien financier de la région Ile de France et du LabEx Charmmmat sur la base d'un partenariat regroupant plusieurs laboratoire du LabEx, (LAMBE, LPPSM, ICMMO, ILV), cet instrument a été installé sur le site d'Evry du LAMBE (Bâtiment Maupertuis – Université d'Evry val d'Essonne) fin juin 2015.

L'instrument acquis est un spectromètre de masse de type piège ionique 3D de dernière génération (Bruker Amazon Speed ETD), équipé de deux sources d'ionisation (electrospray et CaptiveSpray, permettant une gamme de débit étendue), et d'un module ETD/PTR (Electron Transfer Dissociation/Proton Transfer Reaction), permettant, par réactivité en phase gazeuse, de modifier si besoin le nombre et la nature des charges des ions formés par electrospray. Cet instrument peut être couplé à la chromatographie liquide ou à l'électrophorèse capillaire.

Lire la suite...

Journée scientifique annuelle 2014

Le LabEx CHARM3AT organise une journée de conférences le 30 juin à l'ENS Cachan autour des thématiques :

  • de la catalyse
  • de la caractérisation des systèmes moléculaires
  • des matériaux. 

Télécharger l'affiche avec le programme.

Résultats de recherche

Liste des publications par année

2016 - 2015 - 2014 - 2013

 

2016

 

Asymmetric Assisted Tandem Catalysis: Hydroamination followed by Asymmetric Friedel-Crafts Reaction from a Single Chiral N,N,N’,N’-Tetradentate Pyridylmethylamine-Based Ligand.
A. Aillerie, V. Rodriguez-Ruiz, R. Carlino, F. Bourdreux, R. Guillot, S. Bezzenine-Lafollee, R. Gil, D. Prim, J. Hannedouche, ChemCatChem 2016, 8, 2455-2460.

Complexes of the tripodal phosphine ligands PhSi(XPPh2)(3) (X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2.
A. Aloisi, J.-C. Berthet, C. Genre, P. Thuery, T. Cantat, Dalt. Trans. 2016, 45, 14774-14788.

Investigating the Case of Titanium(IV) Carboxyphenolate Photoactive Coordination Polymers.
H. Assi, L. C. P. Perez, G. Mouchaham, F. Ragon, M. Nasalevich, N. Guillou, C. Martineau, H. Chevreau, F. Kapteijn, J. Gascon, P. Fertey, E. Elkaim, C. Serre, T. Devic, Inorg. Chem. 2016, 55, 7192-7199.

The Multiple Facets of Iodine(III) Compounds in an Unprecedented Catalytic Auto-amination for Chiral Amine Synthesis.
J. Buendia, G. Grelier, B. Darses, A. G. Jarvis, F. Taran, P. Dauban, Angew. Chem. Int. Ed. 2016, , 7530-7533.

Self-assembled monolayer formation of a (N-5)Fe(II) complex on gold electrodes: electrochemical properties and coordination chemistry on a surface.
C. Buron, S. Groni, N. Segaud, S. Mazerat, D. Dragoe, C. Fave, K. Senechal-David, B. Schollhorn, F. Banse, Dalt. Trans. 2016, 45, 19053-19061.

Electrodeposition of Polypyrenes with Tunable Hydrophobicity, Water Adhesion, and Fluorescence Properties.
G. R. Chagas, X. Xie, T. Darmanin, K. Steenkeste, A. Gaucher, D. Prim, R. Meallet-Renault, G. Godeau, S. Amigoni, F. Guittard, J. Phys. Chem. C 2016, 120, 7077-7087.

Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes.
C. Chauvier, P. Thuery, T. Cantat, Angew. Chem. Int. Ed. 2016, 55, 14096-14100.

Metal-free disproportionation of formic acid mediated by organoboranes.
C. Chauvier, P. Thuery, T. Cantat, Chem. Sci. 2016, 7, 5680–5685.

Rhodium-Catalyzed Alkene Difunctionalization with Nitrenes.
J. Ciesielski, G. Dequirez, P. Retailleau, V. Gandon, P. Dauban, Chem. Eur. J. 2016, 22, 9338-9347.

Mixing and matching chiral cobalt- and manganese-based calix-salen catalysts for the asymmetric hydrolytic ring opening of epoxides.
H. Dandachi, E. Zaborova, E. Kolodziej, O. R. P. David, J. Hannedouche, M. Mellah, N. Jaber, E. Schulz, Tetrahedron: Asymmetry 2016, 27, 246–253.

Sequential Copper-Catalyzed Alkyne–Azide Cycloaddition and Thiol-Maleimide Addition for the Synthesis of Photo- and/or Electroactive Fullerodendrimers and Cysteine-Functionalized Fullerene Derivatives.
H. Fensterbank, K. Baczko, C. Constant, N. Idttalbe, F. Bourdreux, A. Vallée, A.-M. Goncalves, R. Méallet-Renault, G. Clavier, K. Wright, E. Allard, J. Org. Chem. 2016, 81, 8222-8233.

Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters.
S. Feuillastre, M. Pauton, L. Gao, A. Desmarchelier, A. J. Riives, D. Prim, D. Tondelier, B. Geffroy, G. Muller, G. Clavier, G. Pieters, J. Am. Chem. Soc. 2016, 138, 3990–3993.

Deciphering the Conformational Choreography of Zinc Coordination Complexes with Standard and Novel Proton NMR Techniques Combined with DFT Methods.
J. E. Herbert Pucheta, D. Prim, J. M. Gillet, J. Farjon, ChemPhysChem 2016, 17, 1034-1045.

Oxidation catalysis via visible-light water activation of a [Ru(bpy)3]2+ chromophore BSA-metallocorrole couple.
C. Herrero, A. Quaranta, R. Ricoux, A. Trehoux, A. Mahammed, Z. Gross, F. Banse, J.-P. Mahy, Dalt. Trans. 2016, 45, 706–710.

alpha-Carbamoylsulfides as N-Carbamoylimine Precursors in the Visible Light Photoredox-Catalyzed Synthesis of alpha,alpha-Disubstituted Amines.
C. Lebee, M. Languet, C. Allain, G. Masson, Org. Lett. 2016, 18, 1478-1481.

Synthesis, structure and electrochemical behavior of new RPONOP (R = tBu, iPr) pincer complexes of Fe2+,Co2+, Ni2+, and Zn2+ ions.
C. Lescot, S. Savourey, P. Thuery, G. Lefevre, J.-C. Berthet, T. Cantat, CR Chim. 2016, 19, 57-70.

Iron-Mediated Domino Interrupted Iso-Nazarov/Dearomative (3+2)-Cycloaddition of Electrophilic Indoles.
A.-S. Marques, V. Coeffard, I. Chataigner, G. Vincent, X. Moreau, Org. Lett. 2016, 18, 5296-5299.

Proton-Conducting Phenolate-Based Zr Metal-Organic Framework: A Joint Experimental-Modeling Investigation.
P. G. M. Mileo, S. Devautour-Vinot, G. Mouchaham, F. Faucher, N. Guillou, A. Vimont, C. Serre, G. Maurin, J. Phys. Chem. C 2016, 120, 24503-24510.

Calcium-Catalyzed Synthesis of Polysubstituted 2-Alkenylfurans from beta-Keto Esters Tethered to Propargyl Alcohols.
S. P. Morcillo, D. Leboeuf, C. Bour, V. Gandon, Chem. Eur. J. 2016, 22, 16972-16976.

Site-Selective Calcium-Catalyzed/Organocatalyzed Condensation of Propargyl Alcohols Tethered to beta-Keto Esters.
S. P. Morcillo, M. Presset, S. Floquet, V. Coeffard, C. Greck, C. Bour, V. Gandon, Eur. J. Org. Chem. 2016, 2688-2694.

Heteroanionic Materials Based on Copper Clusters, Bisphosphonates, and Polyoxometalates: Magnetic Properties and Comparative Electrocatalytic NOx Reduction Studies.
O. Oms, S. Yang, W. Salomon, J. Marrot, A. Dolbecq, E. Riviere, A. Bonnefont, L. Ruhlmann, P. Mialane, Inorg. Chem. 2016, 55, 1551-1561.

Design of Laccase-Metal Organic Framework-Based Bioelectrodes for Biocatalytic Oxygen Reduction Reaction.
S. Patra, S. Sene, C. Mousty, C. Serre, A. Chausse, L. Legrand, N. Steunou, ACS Appl. Mater. Interfaces 2016, 8, 20012-20022.

Electron transfer activity of a de novo designed copper center in a three-helix bundle fold.
J. S. Plegaria, C. Herrero, A. Quaranta, V. L. Pecoraro, BBA-Bioenergetics 2016, 1857, 522-530.

Enhanced Depth Profiling of Perovskite Oxide: Low Defect Levels Induced in SrTiO3 by Argon Cluster Sputtering.
K. Ridier, D. Aureau, B. Berini, Y. Dumont, N. Keller, J. Vigneron, A. Etcheberry, A. Fouchet, J. Phys. Chem. C 2016, 120, 21358-21363.

Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal-Organic Framework Matrices.
W. Salomon, Y. Lan, E. Riviere, S. Yang, C. Roch-Marchal, A. Dolbecq, C. Simonnet-Jegat, N. Steunou, N. Leclerc-Laronze, L. Ruhlmann, T. Mallah, W. Wernsdorfer, P. Mialane, Chem. Eur. J. 2016, 22, 6564-6574.

Synergistic effects in ambiphilic phosphino-borane catalysts for the hydroboration of CO2.
A. Tlili, A. Voituriez, A. Marinetti, P. Thuery, T. Cantat, Chem. Commun. 2016, 52, 7553-7555.

Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs.
N. von Wolff, G. Lefevre, J.-C. Berthet, P. Thuery, T. Cantat, ACS Catal. 2016, 6, 4526-4535.

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2015

 

Tuning the Dimensionality of Polyoxometalate-Based Materials by Using a Mixture of Ligands.

G. Rousseau, L. M. Rodriguez-Albelo, W. Salomon, P. Mialane, J. Marrot, F. Doungmene, I.-M. Mbomekallé, P. de Oliveira, A. Dolbecq, Crystal Growth & Design 2015, 15, 449-456

 

Immobilization of Polyoxometalates in the Zr-based Metal Organic Framework UiO-67.

W. Salomon, C. Roch-Marchal, P. Mialane, P. Rouschmeyer, C. Serre, M. Haouas, F. Taulelle, S. Yang, L. Ruhlmann, A. Dolbecq, Chem. Commun. 2015, 51, 2972-2975.

 

Reductive functionalization of CO2 with amines: An entry to formamide, formamidine and methylamine derivatives.

A. Tlili, E. Blondiaux, X. Frogneux, T. Cantat, Green Chemistry 2015, 17, 157-168.

 

Tandem Catalytic C(sp(3))-H Amination/Sila-Sonogashira-Hagihara Coupling Reactions with Iodine Reagents.

J. Buendia, B. Darses, P. Dauban, Angew. Chem. Int. Ed. 2015, 54, 5697-5701.

 

Metal-free disproportionation of formic acid mediated by organoboranes.

C. Chauvier, A. Tlili, C. Das Neves Gomes, P. Thuery, T. Cantat, Chem. Sci. 2015, 6, 2938-2942.

 

Successive light-induced two electron transfers in a Ru-Fe supramolecular assembly: from Ru-Fe(II)-OH2 to Ru-Fe(IV)-oxo.

C. Herrero, A. Quaranta, M. Sircoglou, K. Senechal-David, A. Baron, I. M. Marin, C. Buron, J.-P. Baltaze, W. Leibl, A. Aukauloo, F. Banse, Chem. Sci. 2015, 6, 2323-2327.

 

Mechanochromic Luminescence of Copper Iodide Clusters.

Q. Benito, I. Maurin, T. Cheisson, G. Nocton, A. Fargues, A. Garcia, C. Martineau, T. Gacoin, J.-P. Boilot, S. Perruchas, Chem. Eur. J. 2015, 21, 5892-5897.

 

Understand, elucidate and rationalize the coordination mode of pyrimidylmethylamines: an intertwined study combining NMR and DFT methods.

J. E. Herbert Pucheta, M. Candy, O. Colin, A. Requet, F. Bourdreux, E. Galmiche-Loire, A. Gaucher, C. Thomassigny, D. Prim, M. Mahfoudh, E. Leclerc, J. M. Campagne, J. Farjon, Phys. Chem. Chem.Phys. 2015, 17, 8740-8749.

 

Pushing the limits of signal resolution to make coupling measurement easier.

J. E. Herbert Pucheta, D. Pitoux, C. M. Grison, S. Robin, D. Merlet, D. J. Aitken, N. Giraud, J. Farjon, Chem. Commun. 2015, 51, 7939-7942.

 

Diindeno[1,2-b:2',1'-n]Perylene: a Closed Shell related Chichibabin’s Hydrocarbon, Synthesis, Molecular Packing, Electronic and Charge Transport Properties.

K. Sbargoud, M. Mamada, J. Marrot, S. Tokito, A. Yassar, M. Frigoli, Chem. Sci. 2015, 6, 3402-3409.

 

Intra-residue interactions in proteins: interplay between serine or cysteine side chains and backbone conformations, revealed by laser spectroscopy of isolated model peptides.
M. Alauddin, H. S. Biswal, E. Gloaguen, M. Mons, Phys. Chem. Chem. Phys. 2015, 17, 2169-2178.

 

Intrinsic Folding Proclivities in Cyclic -Peptide Building Blocks: Configuration and Heteroatom Effects Analyzed by Conformer-Selective Spectroscopy and Quantum Chemistry.

M. Alauddin, E. Gloaguen, V. Brenner, B. Tardivel, M. Mons, A. Zehnacker-Rentien, V. Declerck, D. J. Aitken, Chem. Eur. J. 2015, 21, 16479-16493.

 

Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes.

E. Bernoud, C. Lepori, M. Mellah, E. Schulz, J. Hannedouche, Catal. Sci. Technol. 2015, 5, 2017-2037.

 

An Artificial Enzyme Made by Covalent Grafting of an Fe-II Complex into beta-Lactoglobulin: Molecular Chemistry, Oxidation Catalysis, and Reaction-Intermediate Monitoring in a Protein.
C. Buron, K. Senechal-David, R. Ricoux, J.-P. Le Caer, V. Guerineau, P. Mejanelle, R. Guillot, C. Herrero, J.-P. Mahy, F. Banse, Chem. Eur. J. 2015, 21, 12188-12193.

 

Three-Component Photoredox-Mediated Chloro-, Bromo-, or Iodotrifluoromethylation of Alkenes.
A. Carboni, G. Dagousset, E. Magnier, G. Masson, Synthesis-Stuttgart 2015, 47, 2439-2445.


Monoanionic Dipyrrin-Pyridine Ligands: Synthesis, Structure and Photophysical Properties.
C. Ducloiset, P. Jouin, E. Paredes, R. Guillot, M. Sircoglou, M. Orio, W. Leibl, A. Aukauloo, Eur. J. Inorg. Chem. 2015, 5405-5410.


Room Temperature Organocatalyzed Reductive Depolymerization of Waste Polyethers, Polyesters, and Polycarbonates.
E. Feghali, T. Cantat, ChemSusChem 2015, 8, 980-984.


Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals.
X. Frogneux, E. Blondiaux, P. Thuery, T. Cantat, ACS Catal. 2015, 5, 3983-3987.


Tunable Keplerate Type-Cluster ``Mo-132{’’} Cavity with Dicarboxylate Anions.
T.-L. Lai, M. Awada, S. Floquet, C. Roch-Marchal, N. Watfa, J. Marrot, M. Haouas, F. Taulelle, E. Cadot, Chem. Eur. J. 2015, 21, 13311-13320.


A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs.
G. Mouchaham, L. Cooper, N. Guillou, C. Martineau, E. Elkaim, S. Bourrelly, P. L. Llewellyn, C. Allain, G. Clavier, C. Serre, T. Devic, Angew. Chem. Int. Ed. 2015, 54, 13297-13301.


Synergistic ``ping-pong’’ energy transfer for efficient light activation in a chromophore-catalyst dyad.
A. Quaranta, G. Charalambidis, C. Herrero, S. Margiola, W. Leibl, A. Coutsolelos, A. Aukauloo, Phys. Chem. Chem. Phys. 2015, 17, 24166-24172.


Regio- and stereoselective synthesis of alpha-hydroxy-beta-azido tetrazoles.
P. Quinodoz, C. Lo, M. Kletskii, O. Burov, J. Marrot, F. Couty, Org. Chem. Front. 2015, 2, 492-496.


Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C-N, C-O and C-P bond.
V. Rodriguez-Ruiz, R. Carlino, S. Bezzenine-Lafollee, R. Gil, D. Prim, E. Schulz, J. Hannedouche, Dalt. Trans. 2015, 44, 12029-12059.

 

Electrochemical study of a nonheme Fe(II) complex in the presence of dioxygen. Insights into the reductive activation of O-2 at Fe(II) centers.
N. Segaud, E. Anxolabehere-Mallart, K. Senechal-David, L. Acosta-Rueda, M. Robert, F. Banse, Chem. Sci. 2015, 6, 639-647.


Reductive functionalization of CO2 with amines: an entry to formamide, formamidine and methylamine derivatives.
A. Tlili, E. Blondiaux, X. Frogneux, T. Cantat, Green Chem. 2015, 17, 157-168.


Catalytic oxidation of dibenzothiophene and thioanisole by a diiron(III) complex and hydrogen peroxide.
A. Trehoux, Y. Roux, R. Guillot, J.-P. Mahy, F. Avenier, J. Mol. Catal. A-Chem. 2015, 396, 40-46.

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2014 

 

Fabrication and characterization of all-covalent nanocomposite functionalized screen-printed, voltammetric sensors

J.-P. Jasmin, C. Cannizzo, E. Dumas, A. Chaussé, Electrochimica Acta 2014, 133, 467-474.

 

Creating added value with a waste: Methylation of amines with CO2 and H2

A. Tlili, X. Frogneux, E. Blondiaux, T. Cantat, Angew. Chem. Int. Ed. 2014, 53, 2543-2545.

 

Immobilization of Co-containing Polyoxometalates in MIL-101(Cr) : Structural Integrity versus Chemical Transformation

W. Salomon, F.-J. Yazigi, C. Roch-Marchal, P. Mialane, P. Horcajada, C. Serre, M. Haouas, F. Taulelle, A. Dolbecq, Dalton Trans. 2014, 43, 12698-12705.

 

One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

A. Carboni, G. Dagousset, E. Magnier, G. Masson, Chem. Commun. 2014, 50, 14197-14200.

 

Photoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of Alkenes

G. Dagousset, A. Carboni, E. Magnier, G. Masson, Org. Lett. 2014, 16, 4340-4343.

.

Photoredox-Induced Three-Component Oxy-, Amino-, and Carbotrifluoromethylation of Enecarbamates

    A. Carboni, G. Dagousset, E. Magnier, G. Masson, Org. Lett. 2014, 16, 1240-1243.

 

Controlled Self-Assembly of Hexa-peri-hexabenzocoronenes in Solution

J. Wu, A. Fechtenkötter, J. Gauss, M. D. Watson, M. Kastler, C. Fechtenkötter, M. Wagner, K. Müllen, J. Am. Chem. Soc. 2004, 126, 11311-11321.

.

Catalytic intermolecular alkene oxyamination with nitrenes

    G. Dequirez, J. Ciesielski, P. Retailleau, P. Dauban, Chem. Eur. J. 2014, 20, 8929-8933.

 

Catalytic C–H Amination: A reaction now accessible to engineered natural enzymes

J.-P. Mahy, J. Ciesielski, P. Dauban, Angew. Chem. Int. Ed. 2014, 53, 6862-6864.

.

Electrochemical Implication of a Hydrogen-Bonded Imidazole on a Redox-Active-Bound Phenolate Group

S. El Ghachtouli, B. Lassalle-Kaiser, R. Guillot, A. Aukauloo, Eur. J. Inorg. Chem. 2014, 2014, 4750-4755.

 

Intramolecular Photoinduced Electron Transfer in Cobalt(II) Chlathrochelate-Zinc Porphyrin Assemblies Leading to Long-Lived Co(I) Species

S. El Ghachtouli, R. Guillot, W. Leibl, A. Aukauloo, J.Porph. Phthal. 2014, 18, 1125-1130.

 

A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production

S. Cherdo, S. E. Ghachtouli, M. Sircoglou, F. Brisset, M. Orio, A. Aukauloo, Chem. Commun. 2014, 50, 13514-13516.

 

Chiral calix-salen cobalt complexes, catalysts for the enantioselective dynamic hydrolytic kinetic resolution of epibromohydrin

H. Dandachi, H. Nasrallah, F. Ibrahim, X. Hong, M. Mellah, N. Jaber, E. Schulz, J. Mol. Catal. A: Chem. 2014, 395, 457-462.

 

    Carbon dioxide reduction via light activation of a ruthenium-Ni(cyclam) complex

C. Herrero, A. Quaranta, S. El Ghachtouli, B. Vauzeilles, W. Leibl, A. Aukauloo, Phys. Chem. Chem.Phys. 2014, 16, 12067-12072.

 

A. Helicene-like chiral auxiliaries in asymmetric catalysis.
P. Aillard, A. Voituriez, A.; Marinetti, Dalt. Trans. 2014, 43, 15263-15278.

Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions.
E. Blondiaux, J. Pouessel, T. Cantat, T., Angew. Chemie Int. Ed. 2014, 53, 12186-12190.

Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes.
E. Feghali, T. Cantat, Chem. Commun. 2014, 50, 862-865.

Catalytic hydrosilylation of oxalic acid: chemoselective formation of functionalized C-2-products.
E. Feghali, O. Jacquet, P. Thuery, T. Cantat, Catal. Sci. Technol. 2014, 4, 2230-2234.

Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines.
X. Frogneux, O. Jacquet, T. Cantat, Catal. Sci. Technol. 2014, 4, 1529-1533.

A Phosphine-Catalyzed Preparation of 4-Arylidene-5-imidazolones.
S. Gabillet, O. Loreau, S. Specklin, E. Rasalofonjatovo, F. Taran, J. Org. Chem. 2014, 79, 9894-9898.

Direct Spectroscopic Evidence of Hyperconjugation Unveils the Conformational Landscape of Hydrazides.
E. Gloaguen, V. Brenner, M. Alauddin, B. Tardivel, M. Mons, A. Zehnacker-Rentien, V. Declerck, D. J. Aitken, Angew. Chemie Int. Ed. 2014, 53, 13756-13759.

Metal-Free Reduction of CO2 with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO2 to Methanol.
C. D. N. Gomes, E. Blondiaux, P. Thuery, T. Cantat, Chem. Eur. J. 2014, 20, 7098-7106.

Visible-emitting hybrid sol-gel materials comprising lanthanide ions: thin film behaviour and potential use as phosphors for solid-state lighting.
X. Huang, G. Zucchi, J. Tran, R. B. Pansu, A. Brosseau, B. Geffroy, F. Nief, New J. Chem. 2014, 38, 5793-5800.

On the near UV photophysics of a phenylalanine residue: conformation-dependent pi-pi* state deactivation revealed by laser spectroscopy of isolated neutral dipeptides.
Y. Loquais, E. Gloaguen, M. Alauddin, V. Brenner, B. Tardivel, M. Mons, Phys. Chem. Chem. Phys. 2014, 16, 22192-22200.

Efficient Disproportionation of Formic Acid to Methanol Using Molecular Ruthenium Catalysts.
S. Savourey, G. Lefevre, J.-C. Berthet, P. Thuery, C. Genre, T. Cantat, Angew. Chemie Int. Ed. 2014, 53, 10466-10470.

One-Pot Synthesis of 1,4-Disubstituted Pyrazoles from Arylglycines via Copper-Catalyzed Sydnone-Alkyne Cycloaddition Reaction.
S. Specklin, E. Decuypere, L. Plougastel, S. Aliani, F. Taran, J. Org. Chem. 2014, 79, 7772–7777.

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2013 

 

Electrochemically monitored fluorescence on plasmonic gratings: A first step toward smart displays with multiple inputs.

F. Miomandre, J.F. Audibert, Q. Zhou, P. Audebert, P. Martin, J.C. Lacroix, Electrochim. Acta. 2013, 110, 56-62.

 

Photoactive Hybrid Gelators Based on a Luminescent Inorganic [Cu4I4] Cluster Core

Q. Benito, A. Fargues, A. Garcia, S. Maron, T. Gacoin, J.-P. Boilot, S. Perruchas, F. Camerel, Chem. Eur. J. 2013, 19, 15831-15835.

 

Synthesis, characterization, morphological behaviour, and photo- and electroluminescence of highly blue-emitting fluorene-carbazole copolymers with alkyl side-chains of different lengths

A. Sergent, G. Zucchi, R. B. Pansu, M. Chaigneau, B. Geffroy, D. Tondelier, M. Ephritikhine, J. Mat. Chem. C 2013, 1, 3207-3216.

 

Click Chemistry as a Convenient Tool for the Incorporation of a Ruthenium Chromophore and a Nickel-Salen Monomer into a Visible-Light-Active

C. Herrero, L. Batchelor, A. Baron, S. El Ghachtouli, S. Sheth, R. Guillot, B. Vauzeilles, M. Sircoglou, T. Mallah, W. Leibl, A. Aukauloo, Eur. J. Inorg. Chem. 2013, 2013, 494-499.

 

Photoassisted Generation of a Dinuclear Iron(III) Peroxo Species Leading to Oxygen Atom Transfer Reaction

F. Avenier, C. Herrero, W. Leibl, A. Desbois, R. Guillot, J.-P. Mahy, A. Aukauloo, Angew. Chem. Int. Ed. 2013, 52, 3634-3637.

 

Identification of the Different Mechanisms of Activation of a [RuII(tpy)(bpy)(OH2))2+ Catalyst by Modified Ruthenium Sensitizers in Supramolecular Complexes
C. Herrero, A. Quaranta, R.-A. Fallahpour, W. Leibl, A. Aukauloo, J. Phys. Chem. C 2013, 117, 9605-9612.

 

Cobalt-Based Particles Formed upon Electrocatalytic Hydrogen Production by a Cobalt Pyridine Oxime Complex

    S. El Ghachtouli, R. Guillot, F. Brisset, A. Aukauloo, ChemSusChem 2013, 6, 2226-2230.

 

Monometallic Cobalt − Trisglyoximato Complexes as Precatalysts forCatalytic H2 Evolution in Water

S. El Ghachtouli, M. Fournier, S. Cherdo, R. Guillot, M.-F. Charlot, E. Anxolabéhère-Mallart, M. Robert, A. Aukauloo, J. Phys. Chem. C 2013, 117, 17073-17077.

 

Light-induced Tryptophan radical generation in a click modular assembly of sensitizer-Tryptophan residue

S. Sheth, A. Baron, C. Herrero, B. Vauzeilles, A. Aukauloo, W. Leibl, Photochem. Photobiol. Sci. 2013, 12, 1074-1078.

 

pi-Stacking interactions at the service of {[}Cu]-bis(oxazoline) recycling.
D. Didier, E. Schulz, Tetrahedron: Asymmetry 2013, 24, 769-775.

Novel Cyclopentadithiophene-Based D-A Copolymers for Organic Photovoltaic Cell Applications.
F. V. Drozdov, E. N. Myshkovskaya, D. K. Susarova, P. A. Troshin, O. D. Fominykh, M. Y. Balakina, A. V. Bakirov, M. A. Shcherbina, J. Choi, D. Tondelier, M. I. Buzin, S. N. Chvalun, A. Yassar, S. A. Ponomarenko, Macromol. Chem. Phys. 2013, 214, 2144-2156.

Recoverable salen-based macrocyclic chiral complexes; catalysts for enantioselective Henry reactions.
F. Ibrahim, N. Jaber, V. Guerineau, A. Hachem, G. Ibrahim, M. Mellah, E. Schulz, Tetrahedron: Asymmetry 2013, 24, 1395-1401.

Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines.
J. Pouessel, O. Jacquet, T. Cantat, T., ChemCatChem 2013, 5, 3552-3556.

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AAP Recherche 2022

L'appel d'offre recherche CHARMMMAT 2022 est ouvert.

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- 9-13 mai 2022: expertise et classement des projets par les membres du COPIL

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Agenda

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